Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods
Keywords:
Phosphonium, Copper (II) compound, Triphenylphosphine, Ethyl bromoacetateAbstract
Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C2H5COO (CH2PPh3Br)] and its copper (II) complex [C2H5COO (CH2PP3Br)] [Cu2Cl6] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na2 [Cu2Cl6]. Then, using spectroscopic methods, preparation of these compounds was investigated.
References
Aldridge, S., Warwick, P., Evans, N., Vines, S., 2007s. Degradation of TetraphenylPhosphonium Bromide at high pH and it’s effect on radionuclide solubility. Chemodphere, 66(672).
Bhrara, K., Kim, H., Singh, G., 2008. Inhibiting effects of Butyl Triphenyl Phosphonium Bromide on corrosion of mild steel in 0/5 M Sulphuric acid solution and it’s adsorption characteristics. Corros. Sci., 50(27**).
Cerichelli, G., La Mesa, C., Luchetti, L., Mancini, G., 2000. Role of counterions in the catalytic activity and phase equilibria of phosphonium salt in water. Langmuir, 16(166).
Cieniecka-Roslonkiewicz, C., Pernak, J., Feder, J.K., Ramani, A., Robertson, A.J., 2005. Synthesis anti-microbial activities and anti-electrostatic properties of phosphonium-based ionic liquids. Green Chem., 7(855).
Hertly, F.R., 1994. The chemistry of organophosphorus compounds. Vol. 3, New York: John Wiley & Sons.
Incomopoulou, S.M., Andreopoulou, A.K., Soto, A., Kallitsis, J.K., 2005. Voyiatzis, Benzene Beads with controlled release characteristics. J. Contr. Release, 102(223).
Jou, G., Gonzalez, I., Albericio, F., Lloyd-Williams, P., Giralt, E., 1997. Total synthesis of Dehydrodidemnin B. use of uronium and phpsphonium salt coupling reagents in peptide synthesis in solution. J. Org. Chem., 62(354).
Kenawy, E.R., Abdel-Hey, F.I., El-Maged, A.A., Mahmoud, 2006. Biologically active polymers: VII. Synthesis and antimicrobial activities of some cross linked copolymers with quaternary ammonium and phosphonium groups, React. Funct. Polym., 66(419).
Moussaousi, Y., Said, K., 2006. Anionic activation of the witting reaction using a solid-liquid phase transfer: Examination of the medium-, temperature-, base- and phase- transfer catalyst effects. ARKIVOC, 12(1).
Nandurkar, N.S., Bhanage, B.M., 2008. Palladium Bis (2, 2, 6, 6-Tetramethyl-3, 5- Heptanedionate) catalyzed Suzuki, Heck, Sonogashira, and Cyanation reactions. Tetrahedron, 64(3655).
Sons, S.Y., Gong, M.S., 2002. Polymeric humidity sensor using phosphonium salt-containing polymers. Sens. Actuators. B., 86(168).
Terada, M., Kouchi, M., 2006. Novel metal-free lewis and acid catalysis by phosphonium salts through hypervalent interaction. Tetrahedron, 62(401).
Terada, M., Kouchi, M., 2006. Novel metal-free Lewis and acid catalysis by phosphonium salts through hypervalent interaction. Tetrahedron, 62(401).
Tseng, M.C., Kan, H.C., Chu, Y.H., 2007. Reactivity of Trihexyl (Tetradecyl) phosphonium chloride, a room-temperature phosphonium ionic liquid. Tetrahedron let., 48(9085).
Tseng, M.C., Kan, H.C., Chu, Y.H., 2007. Reactivity of Trihexyl (Tetradecyl) phosphonium chloride, a room-temperature phosphonium ionic liquid. Tetrahedron Lett., 48(9085).
Wang, X., Tian, S., 2007. Catalytic cyanosilylation of ketones with simple phosphonium salt. Tetrahedron Let. 48(6010).
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2020 Ali Naghipour, Abozar Bastami, Amir Hossein Ezati
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
