Synthesis and characterization of palladium complexes in combination with Phosphonium salts of 1,3-bis (chloro-methyl)-benzene and benzyl bromide by using stereoscopy methods

Authors

  • Ali Naghipour Department of Chemistry, Faculty of Science, Ilam, Iran
  • Feranak Dadvand Tochaee Department of Chemistry, Faculty of Science, Ilam, Iran
  • Abozar Bastami MA Graduate in Inorganic Chemistry, Payam Noor University of Hamadan, Iran

Keywords:

Phosphonium, Palladium complexes, Phenyl phosphine, 1,3-bis (chloro-methyl)-benzene

Abstract

Phosphonium salts have the general formula R4P+X- and are derived from the sub-ion phosphonium tetrahedral(pH+4), such as phosphonium iodide[p(CH3)+4]-. Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methyl phosphonium iodide. In this project, phosphonium compounds [C6H5(CH2pph3Br)], {C6H4 -1- (CH2Cl) -3- (CH2pph3Cl)} and palladium complexes, [C6H(CH2pph3)]2[pd2cl2Br2], [C6H4 -1- CH2Cl) -3-(CH2pph3)][pd2Cl6] were prepared and characterized. Phosphonium salts was prepared from the reaction of 1,3-bis (chloro-methyl)-benzene and tri-phenyl phosphine. Then, through the reaction between phosphonium compounds andNa2[pd2Cl6] final complexes were prepared. Next phosphonium salt was prepared from the reaction between benzyl bromide and tri-phenyl phosphine. Then, final complexes were prepared through a reaction between phosphonium compounds and Na2[pd2Cl6].

References

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Published

2017-03-22

How to Cite

Naghipour, A. ., Dadvand Tochaee, F. ., & Bastami, A. . (2017). Synthesis and characterization of palladium complexes in combination with Phosphonium salts of 1,3-bis (chloro-methyl)-benzene and benzyl bromide by using stereoscopy methods. Scientific Journal of Review, 6(3), 519-528. Retrieved from http://sjournals.com/index.php/sjr/article/view/58

Issue

Section

Chemistry