Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods

Authors

  • Ali Naghipour Department of Chemistry, Faculty of Science, Ilam University, Iran
  • Abozar Bastami MA Graduate in Inorganic Chemistry, Payam Noor University of Hamadan, Iran, Islamic Republic of
  • Amir Hossein Ezati BSc in Chemical Engineering, Amir Kabir University of Technology, Tehran, Iran, Islamic Republic of

Keywords:

Phosphonium, Copper (II) compound, Triphenylphosphine, Ethyl bromoacetate

Abstract

Phosphonium salts have the general formula  and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl  phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C2H5COO (CH2PPh3Br)] and its copper (II) complex [C2H5COO (CH2PP3Br)] [Cu2Cl6] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na2 [Cu2Cl6]. Then, using spectroscopic methods, preparation of these compounds was investigated.

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Published

2017-05-18

How to Cite

Naghipour, A. ., Bastami, A. ., & Ezati, A. H. . (2017). Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods. Scientific Journal of Review, 6(7), 535-541. Retrieved from http://sjournals.com/index.php/sjr/article/view/62

Issue

Section

Chemistry