Catalytic degradation of toluene on manganese oxide catalyst loaded on a natural zeolite support

Authors

  • Akbar Barzegar Ph.D. Student, Department of Occupational Health, Faculty of Medical Sciences, Tarbiat Modares University, Tehran, Iran. Iran, Islamic Republic of
  • Bagher Mortazavi Department of Occupational Health, Faculty of Medical Sciences, Tarbiat Modares University, Tehran, Iran Iran, Islamic Republic of
  • Hasan Asilian Mahabadi Department of Occupational Health, Faculty of Medical Sciences, Tarbiat Modares University, Tehran, Iran. Iran, Islamic Republic of
  • Hossein Kazemian Deptartment of Chemical and Biochemical Engineering, Western University, London, ON, Canada, N6A 5B9. Canada

Keywords:

Catalytic oxidation; Toluene; Manganese oxide; Clinoptilolite

Abstract

The aim of the present study was the investigation of catalytic oxidation of toluene over manganese oxide supported on a natural zeolite (clinoptilolite). The catalyst was synthesized by the impregnation method and calcining at 450°C, and then characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The effects of the toluene concentration, and space velocity were investigated at different reaction temperatures and the catalytic activity of the catalyst was compared with zeolite 13X. The results indicate that Mn/Clino catalyst, with 10wt% loading, shows proper catalytic activity for degradation of toluene. This study claims that Mn/Clino exhibited relatively a good catalytic activity in comparison with Mn/Z13X.

References

Auvinen, J., Wirtanen, L., 2008. The influence of photocatalytic interior paints on indoor air quality. Atm. Environ. 42(18), 4101-4112.

Avgouropoulos, G., Oikonomopoulos, E., Kanistras, D., Ioannides, T., 2006. Complete oxidation of ethanol over alkali-promoted Pt/Al2O3 catalysts. Appl. Catal. B Environ. 65(1), 62-69.

Barzegar Shangol, A., Mortazavi, S.B., Asilian, H., Kazemian, H., 2013. Elimination of toluene vapours using natural zeolite treated by copper oxide. J. Kermanshah University Med. Sci. 17(7), 423-430.

Corma, A., Navarro, M.T., 2002. From micro to mesoporous molecular sieves: adapting composition and structure for catalysis. Stud. Surf. Sci. Catal. 142, 487-501.

Faghihian, H., Ghannadi Marageh, M., Kazemian, H., 1999. The use of clinoptilolite and its sodium form for removal of radioactive cesium, and strontium from nuclear wastewater and Pb2+, Ni2+, Cd2+, Ba2+ from municipal wastewater. Appl. Rad. Isotop. 50(4), 655-660.

Ghadiri, S., Nabizadeh, R., Mahvi, A., Nasseri, S., Kazemian, H., Mesdaghinia, A., Nazmara, S., 2010. Methyl tert-butyl ether adsorption on surfactant modified natural zeolites. Iran. J. Environ. Health Sci. Eng. 7(3), 235-246.

Kazemian, H., Mallah, M.H., 2008. Removal of chromate ion from contaminated synthetic water using MCM-41/ZSM-5 composite. Iran. J. Environ. Health Sci. Eng. 5(1), 73-77.

Kim, S.C., 2002. The catalytic oxidation of aromatic hydrocarbons over supported metal oxide. J. Hazard. Mater. 91(1), 285-299.

Lahousse, C., Bernier, A., Grange, P., Delmon, B., Papaefthimiou, P., Ioannides, T., Verykios, X., 1998. Evaluation of gamma-MnO2 as a VOC removal catalyst: comparison with a noble metal catalyst. J. Catal. 178(1), 214-225.

Li, W.B., Zhuang, M., Wang, J.X., 2008. Catalytic combustion of toluene on Cu-Mn/MCM-41 catalysts: influence of calcination temperature and operating conditions on the catalytic activity. Catal. Today. 137(2), 340-344.

Mahabadi, A.A., Hajabbasi, M.A., Khademi, H., Kazemian, H., 2007. Soil cadmium stabilization using an iranian natural zeolite. Geoderma. 137(3), 388-393.

Maldonado-Hodar, F.J., Moreno-Castilla, C., Perez-Cadenas, A.F., 2004. Catalytic combustion of toluene on platinum-containing monolithic carbon aerogels. Appl. Catal. B Environ. 54(4), 217-224.

Menhaje-Bena, R., Kazemian, H., Shahtaheri, S.J., Ghazi-Khansari, M., 2004. Removal of arsenic species from drinking water by Iranian natural and synthetic zeolites. Stud. Surf. Sci. Catal. 154, 1892-9.

Mo, J., Zhang, Y., Xu, Q., Lamson, J.J., Zhao, R., 2009. Photocatalytic purification of volatile organic compounds in indoor air: a literature review. Atm. Environ. 43(14), 2229-2246.

Ozcelik, Z., Soylu, G.P., Boz, I., 2009. Catalytic combustion of toluene over Mn, Fe and Co-exchanged clinoptilolite support. Chem. Eng. J. 155(1), 94-100.

Park, P.W., Ledford, J.S., 1998. The influence of surface structure on the catalytic activity of alumina supported copper oxide catalysts: oxidation of carbon monoxide and methane. Appl. Catal. B Environ. 15(3), 221-231.

Santos, V.P., Bastos, S.S.T., Pereira, M.F.R., Ôrfao, J.J.M., Figueiredo, J.L., 2010a. Stability of a cryptomelane catalyst in the oxidation of toluene. Catal. Today. 154(3), 308-311.

Santos, V.P., Pereira, M.F.R., Ôrfao, J.J.M., Figueiredo, J.L., 2010b. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds. Appl. Catal. B Environ. 99(1), 353-363.

Santos, V.P., Carabineiro, S., Tavares, P.B., Pereira, M., Ôrfao, J., Figueiredo, J.L., 2010c. Oxidation of CO, ethanol and toluene over TiO2 supported noble metal catalysts. Appl. Catal. B Environ. 99(1), 198-205.

Seifi, L., Torabian, A., Kazemian, H., Bidhendi, G.N., Azimi, A.A., Nazmara, S., AliMohammadi, M., 2011. Adsorption of BTEX on surfactant modified granulated natural zeolite nanoparticles: parameters optimizing by applying taguchi experimental design method. Clean. Soil. Air. Water. 39(10), 939-948.

Soylu, G.S.P., Ozçelik, Z., Boz, I., 2010. Total oxidation of toluene over metal oxides supported on a natural clinoptilolite-type zeolite. Chem. Eng. J. 162(1), 380-387.

Torabian, A., Kazemian, H., Seifi, L., Bidhendi, G.N., Azimi, A.A., Ghadiri, S.K., 2010. Removal of petroleum aromatic hydrocarbons by surfactant-modified natural zeolite: the effect of surfactant. Clean. Soil. Air. Water. 38(1), 77-83.

Tsou, J., Magnoux, P., Guisnet, M., Orfao, J.J.M., Figueiredo, J., 2005. Catalytic oxidation of volatile organic compounds: oxidation of methyl-isobutyl-ketone over Pt/zeolite catalysts. Appl. Catal. B Environ. 57(2), 117-123.

Veser, G., Ziauddin, M., Schmidt, L.D., 1999. Ignition in alkane oxidation on noble-metal catalysts. Catal. Today. 47(1), 219-228.

Vu, V., Belkouch, J., Ould-Dris, A., Taouk, B., 2008. Catalytic oxidation of volatile organic compounds on manganese and copper oxides supported on titania. A.I.Ch.E.J. 54(6), 1585-1591.

Yang, Y., Xu, X., Sun, K., 2007. Catalytic combustion of ethyl acetate on supported copper oxide catalysts. J. Hazard. Mater. 139(1), 140-145.

Published

2014-05-29

How to Cite

Barzegar, A. ., Mortazavi, B. ., Asilian Mahabadi, H. ., & Kazemian, H. . (2014). Catalytic degradation of toluene on manganese oxide catalyst loaded on a natural zeolite support. Scientific Journal of Review, 3(5), 345-352. Retrieved from http://sjournals.com/index.php/sjr/article/view/559

Issue

Section

Environmental Sciences